Biblio

Hexagonal CdS and Fe-doped CdS nanorods were synthesised by a facile hydrothermal method and characterised by X-ray diffraction, energy dispersive X-ray spectroscopy, UV-vis absorption, photoluminescence, and X-ray photoelectron spectroscopy. The magnetic properties of undoped and Fe-doped CdS nanorods were investigated at room temperature. The experimental results demonstrate that the ferromagnetism of the Fe-doped CdS nanorods differs from that of the undoped CdS nanorods. The remanence magnetisation (Mr) and the coercive field (Hc) of the Fe-doped CdS nanorods were 4.9 × 10-3 emu/g and 270.6 Oe, respectively, while photoluminescence properties were not influenced by doping. First-principle calculations show that the ferromagnetism in Fe-doped CdS nanocrystal arose not only from the Fe dopants but also from the Cd vacancies, although the main contribution was due to the Fe dopants.

A Unique Object (UNO) is a physical object with unique characteristics that can be measured externally. The usually analogue measurement can be converted into a digital representation - a fingerprint - which uniquely identifies the object. For practical applications it is necessary that measurements can be performed without the need of specialist equipment or complex measurement setup. Furthermore, a UNO should be able to defeat simulation attacks; an attacker may replace the UNO with a device or system that produces the expected measurement. Recently a novel type of UNOs based on Quantum Dots (QDs) and exhibiting unique photo-luminescence properties has been proposed. The uniqueness of these UNOs is based on quantum effects that can be interrogated using a light source and a camera. The so called Quantum Confinement UNO (QCUNO) responds uniquely to different light excitation levels which is exploited for simulation attack protection, as opposed to focusing on features too small to reproduce and therefore difficult to measure. In this paper we describe methods for extraction of fingerprints from the QCUNO. We evaluate our proposed methods using 46 UNOs in a controlled setup. Focus of the evaluation are entropy, error resilience and the ability to detect simulation attacks.