Biblio

The relationship between magnetic domain structures and magnetic properties of Nd-doped Sm(Fe, Cu, Zr, Co)7.5 was investigated. In the preparation process, slow cooling between sintering and solution treatment was employed to promote homogenization of microstructures. The developed magnet achieved a maximum energy product, [BH]m, of 33.8 MGOe and coercivity, Hcb, of 11.2 kOe at 25 °C, respectively. Moreover, B-H line at 150 °C was linear, which means that irreversible demagnetization does not occur even at 150 °C. Temperature coefficients of remanent magnetic flux density, Br, and intrinsic coercivity, Hcj, were 0.035%/K and 0.24%/K, respectively, as usual the conventional Sm-Co magnet. Magnetic domain structures were observed with a Kerr effect microscope with a magnetic field applied from 0 to -20 kOe, and then reverse magnetic domains were generated evenly from grain boundaries. Microstructures referred to as “cell structures” were observed with a scanning transmission electron microscope. Fe and Cu were separated to 2-17 and 1-5 phases, respectively. Moreover, without producing impurity phases, Nd showed the same composition behavior with Sm in a cell structure.

Hexagonal CdS and Fe-doped CdS nanorods were synthesised by a facile hydrothermal method and characterised by X-ray diffraction, energy dispersive X-ray spectroscopy, UV-vis absorption, photoluminescence, and X-ray photoelectron spectroscopy. The magnetic properties of undoped and Fe-doped CdS nanorods were investigated at room temperature. The experimental results demonstrate that the ferromagnetism of the Fe-doped CdS nanorods differs from that of the undoped CdS nanorods. The remanence magnetisation (Mr) and the coercive field (Hc) of the Fe-doped CdS nanorods were 4.9 × 10-3 emu/g and 270.6 Oe, respectively, while photoluminescence properties were not influenced by doping. First-principle calculations show that the ferromagnetism in Fe-doped CdS nanocrystal arose not only from the Fe dopants but also from the Cd vacancies, although the main contribution was due to the Fe dopants.

In this paper, we present a study about the remanence state and coercivity in 1-D chain of cobalt hollow nanospheres, by using micromagnetic simulation. The high coercivity values (Hc is determined in the range of 600-1800 Oe) and the monotonic decrease of remanence are attributed to the shape anisotropy effect due to an increase in the aspect ratio value. The configuration of magnetization in remanence showed the onion state for hollow spheres (HSs) with Re = 15 nm, whereas for Re = 30 nm, appear the curling-vortex (CV) state. Finally for a cluster of chains, constituted by cobalt HSs, with random orientations the CV state is preserved.

Macroscopic hysteresis loops and microscopic magnetic moment distributions have been determined by 3-D model for Co nanowire with various easy axis deviations from applied field. It is found that both the coercivity and the remanence decrease monotonously with the increase of easy axis deviation as well as the maximum magnetic product, indicating the large impact of the easy axis orientation on the magnetic performance. Moreover, the calculated angular distributions and the evolution of magnetic moments have been shown to explain the magnetic reversal process. It is demonstrated that the large demagnetization field in the two ends of the nanowire makes the occurrence of reversal domain nucleation easier, hence the magnetic reversal. In addition, the magnetic reversal was illustrated in terms of the analysis of the energy evolution.

High-temperature magnetic properties of the anisotropic bulk SmCo7/Fe(Co) nanocomposite magnets prepared by multistep deformation have been investigated and compared with the corresponding isotropic nanocomposites. The anisotropic SmCo7/Fe(Co) nanocomposites with a Fe(Co) fraction of 28% exhibit much higher energy products than the corresponding isotropic nanocomposites at both room and high temperatures. These magnets show a small remanence (α = -0.022%/K) and a coercivity (β = -0.25%/K) temperature coefficient which can be comparable to those of the conventional SmCo5 and Sm2Co17 high-temperature magnets. The magnetic properties of these nanocomposites at high temperatures are sensitive to the weight fractions of the Fe(Co) phase. This paper demonstrates that the anisotropic bulk SmCo7/Fe(Co) nanocomposites have better high-temperature magnetic properties than the corresponding isotropic ones.

The discovery of the interstitial rare earth nitride Sm2Fe17N3 came about seven years after the discovery of the rare earth iron boride Nd2Fe [1],[2], and the nitride initially seemed to offer intrinsic magnetic properties that were superior (Curie temperature TC, magnetocrystalline anisotropy K1 or comparable (spontaneous magnetization Ms to those of its illustrious predecessor. However, the promise of the new material to seriously challenge Nd2Fe14B was not realized. The 2:17 nitride powder, prepared by a low-temperature gas-phase interstitial modification process proved difficult to orient and worse still, it lost its nitrogen at the temperatures needed to process dense sintered magnets [3]. Attempts at explosive compaction [4] or spark sintering [5] failed to yield material with good enough coercivity. Nevertheless, work continued in Japan and China to develop a coercive powder that could be used for bonded magnets. An early realization was zinc-bonded Sm2Fe17N3 [6] with an energy product of 84 kJm3 but a rather low coercivity of 480 kAm-1, less than 5 % of the anisotropy field (Ha = 2K1/Ms ≈ 11 MAm-1). The anisotropy field of Nd2Fe14B is significantly less (6 MAm-1) yet several decades of intensive development have led to higher values and continuous improvements of the coercivity, even in unsubstituted material. Historical experience with permanent magnets shows that a long period of materials development is needed to arrive at the best composition and processing conditions for a microstructure that allows the hard magnetism to be optimized. Coercivities of about 25% of the anisotropy field are ultimately achieved. Here we compare the magnetic properties of melt-spun material. Our Nitroquench powder, produced by Daido Steel, was in the form of flakes 10 μm thick and up to 100 μm in diameter. A crystal-lite size of approximately 15 nm deduced from Scherrer broadening of the X-ray reflections. Composition was checked by EDX microprobe analysis. Hysteresis loops have been measured in applied fields of up to 14 T, at room temperature and at 4 K.The material exhibits a room-temperature coercivity of 690 kAm-1 after saturation in 14 T, with a remanence of 700 kAm-1 in zero applied field and an extrapolated saturation magnetization of 1230 kAm-1. The remanence ratio Mr/Ms of 63% when the remanence is corrected to zero internal field, is reflected in a preferred orientation seen in the X-ray powder diffraction patterns and in 57Fe Mössbauer spectra of magnetized powder. Spectra obtained after saturation of an immobilized powder absorber either in-plane or perpendicular to the sample plane exhibit distinctly different relative intensities of the ΔM=0 absorption lines. The maximum energy product for the powder, assuming full density, is 162 kJm-3. The remanence enhancement is attributed to fact that the nanocrystallite size is not much greater than the exchange length. Melt-spun Sm-Fe-N powder has superior corrosion resistance and thermal stability compared to melt-spun Nd-Fe-B. The Nitroquench powder may be used to produce polymer-bonded magnets with an energy product in excess of 100 kJm-3.

Tensile residual stresses combined with an applied tensile stress can reduce the reliability of steel components. Nondestructive evaluation of residual stress is thus important to avoid unintended fatigue or cracking. Because magnetic hysteresis properties of ferromagnetic materials are sensitive to stress, nondestructive evaluation of residual stress through magnetic properties can be expected. The spatial mapping of local magnetic hysteresis properties becomes possible by using the acoustically stimulated electromagnetic (ASEM) method and the tensile stress dependence of the hysteresis properties has been investigated in steel. It is found that the coercivity Hc and the remanent magnetization signal Vr monotonically decrease with increasing the tensile stress. In this work, we verified the detection of residual stresses through the ASEM response in a welded steel plate. Tensile stresses are intentionally introduced on the opposite side of the partially welded face by controlling welding temperatures. We found that Hc and Vr clearly decrease in the welded region, suggesting that the presence of tensile residual stresses is well detected by the hysteresis parameters.

This paper presents a new class of high-performance permanent micro-magnets based on the controlled assembly of cobalt nanorods for the electromagnetic transduction of MEMS. Micromagnets are fabricated using a low temperature fabrication process that yields a dense material exhibiting high coercive field and remanence to saturation magnetization ratio. The cartography of the magnetic induction produced by the sub-millimeter size magnets was obtained using a scanning Hall effect micro-probe microscope. Silicon microcantilevers placed in the vicinity of these magnets were successfully actuated using the Lorentz force with low currents. The good signal to noise ratio measured at resonance demonstrates the potentiality of these nanostructured micro-magnets.

Micromagnetic simulations of coercivity as a function of external magnetic field direction were performed for a hexagonal array of hemispherical Permalloy nanocaps. The analysis was based on hysteresis loops for arrangements of nanocaps of variable thickness (5 nm and 10 nm). The angular dependence of coercivity had a maximum at about 80° with respect to the arrangement plane. An increase in coercivity with nanocap thickness is related to the magnetization reversal mechanism, where the dipole energy of individual caps generates an effective intermediate axis, locking the magnetic moments. The coercivity has maximum values of 109 Oe for 5 nm and 156 Oe for 10 nm thickness. The remanence decreases monotonically with angle. This is associated with the influence of shape anisotropy, where the demagnetizing field in the plane of the array is much smaller than the demagnetizing field perpendicular to the plane.

Having significant role in the storing, delivering and conversion of the energy, the permanent magnets are key elements in the actual technology. In many applications, the gap between ferrites and rare earths (RE) based sintered permanent magnets is nowadays filled by RE bonded magnets, used in more applications, below their magnetic performances. Therewith, the recent trends in the RE market concerning their scarcity, impose EU to consider alternative magnets (without RE) to fill such gap. The paper presents the chemical synthesis of the exchange coupled SrFe12O19/CoFe2O4 nanocomposites, based on nanoferrites. The appropriate annealing leads to the increasing of the main magnetic characteristics, saturation magnetization MS and intrinsic coercivity Hc, in the range of 49 - 53 emu/g, respectively 126.5 - 306 kA/m. The value reached for the ratio between remanent magnetization and saturation magnetization is higher than 0.5, fact that proved that between the two magnetic phases occurred exchange interaction.

Alternatives to rare earth permanent magnets, such as alnico, will reduce supply instability, increase sustainability, and could decrease the cost of permanent magnets, especially for high-temperature applications, such as traction drive motors. Alnico magnets with moderate coercivity, high remanence, and relatively high-energy product are conventionally processed by directional solidification and (significant) final machining, contributing to increased costs and additional material waste. Additive manufacturing (AM) is developing as a cost effective method to build net-shape 3-D parts with minimal final machining and properties comparable to wrought parts. This paper describes initial studies of net-shape fabrication of alnico magnets by AM using a laser engineered net shaping (LENS) system. High-pressure gas atomized pre-alloyed powders of two different modified alnico “8” compositions, with high purity and sphericity, were built into cylinders using the LENS process, and followed by heat treatment. The magnetic properties showed improvement over their cast and sintered counterparts. The resulting alnico permanent magnets were characterized using scanning electron microscopy, energy dispersive spectroscopy, electron backscatter diffraction, and hysteresisgraph measurements. These results display the potential for net-shape processing of alnico permanent magnets for use in next generation traction-drive motors and other applications requiring high temperatures and/or complex engineered part geometries.

In order to investigate the relationship and effect on the performance of magnetic modulator among applied DC current, excitation source, excitation loop current, sensitivity and induced voltage of detecting winding, this paper measured initial permeability, maximum permeability, saturation magnetic induction intensity, remanent magnetic induction intensity, coercivity, saturated magnetic field intensity, magnetization curve, permeability curve and hysteresis loop of main core 1J85 permalloy of magnetic modulator based on ballistic method. On this foundation, employ curve fitting tool of MATLAB; adopt multiple regression method to comprehensively compare and analyze the sum of squares due to error (SSE), coefficient of determination (R-square), degree-of-freedom adjusted coefficient of determination (Adjusted R-square), and root mean squared error (RMSE) of fitting results. Finally, establish B-H curve mathematical model based on the sum of arc-hyperbolic sine function and polynomial.

Several applications adopt electromagnetic sensors, that base their principle on the presence of magnets realized with specific magnetic materials that show a rather high remanence, but low coercivity. This work concerns the production, analysis and characterization of hybrid composite materials, with the use of metal powders, which aim to reach those specific properties. In order to obtain the best coercivity and remanence characteristics various "recipes" have been used with different percentages of soft and hard magnetic materials, bonded together by a plastic binder. The goal was to find out the interdependence between the magnetic powder composition and the characteristics of the final material. Soft magnetic material (special Fe powder) has been used to obtain a low coercivity value, while hard materials were primarily used for maintaining a good induction remanence; by increasing the soft proportion a higher magnetic permeability has been also obtained. All the selected materials have been characterized and then tested; in order to verify the validity of the proposed materials two practical tests have been performed. Special magnets have been realized for a comparison with original ones (AlNiCo and ferrite) for two experimental cases: the first is consisting in an encoder realized through a toothed wheel, the second regards the special system used for the electric guitars.

Arrays of nanosized hollow spheres of Ni were studied using micromagnetic simulation by the Object Oriented Micromagnetic Framework. Before all the results, we will present an analysis of the properties for an individual hollow sphere in order to separate the real effects due to the array. The results in this paper are divided into three parts in order to analyze the magnetic behaviors in the static and dynamic regimes. The first part presents calculations for the magnetic field applied parallel to the plane of the array; specifically, we present the magnetization for equilibrium configurations. The obtained magnetization curves show that decreasing the thickness of the shell decreases the coercive field and it is difficult to obtain magnetic saturation. The values of the coercive field obtained in our work are of the same order as reported in experimental studies in the literature. The magnetic response in our study is dominated by the shape effects and we obtained high values for the reduced remanence, Mr/MS = 0.8. In the second part of this paper, we have changed the orientation of the magnetic field and calculated hysteresis curves to study the angular dependence of the coercive field and remanence. In thin shells, we have observed how the moments are oriented tangentially to the spherical surface. For the inversion of the magnetic moments we have observed the formation of vortex and onion modes. In the third part of this paper, we present an analysis for the process of magnetization reversal in the dynamic regime. The analysis showed that inversion occurs in the nonhomogeneous configuration. We could see that self-demagnetizing effects are predominant in the magnetic properties of the array. We could also observe that there are two contributions: one due to the shell as an independent object and the other due to the effects of the array.

The inevitable temperature raise leads to the demagnetization of permanent magnet synchronous motor (PMSM), that is undesirable in the application of electrical vehicle. This paper presents a nonlinear demagnetization model taking into account temperature with the Wiener structure and neural network characteristics. The remanence and intrinsic coercivity are chosen as intermediate variables, thus the relationship between motor temperature and maximal permanent magnet flux is described by the proposed neural Wiener model. Simulation and experimental results demonstrate the precision of temperature dependent demagnetization model. This work makes the basis of temperature compensation for the output torque from PMSM.